Product ID:S-T DRAIN OPENER
MSDS Date:05/25/1989
FSC:6850
NIIN:01-100-9946
MSDS Number: BLMWC

SANTEEN PRODUCTS CO

1321 - 7TH STREET S.
HOPKINS, MN 55343
US

Emergency Phone: 612-935-4500/612-435-7530

Info Phone: 612-935-4500

Cage: 0PZ33

SANTEEN PRODUCTS CO INC

HOPKINS, MN 55343 US

Telephone: 612-935-4500

Cage: 0PZ33

SULFURIC ACID (SARA III)

CAS: 7664-93-9

RTECS: WS5600000

Fraction By Weight: 86.0%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:ORAL LD50(RATS) =2140 MG/KG BODY WEIGHT
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE-CORROSIVE.SWALLOWED:CAUSES
MOUTH,THROAT,ESOPHAGUS,STOMACH BURNS,GASTRIC PERFORATION &
DEATH.INHALATION:SEVERE IRRITATION OF THE RESPIRATORY
TRACT,SNEEZING,COUGHING & LUNG DAMAGE.SKIN:BURNING & C
HARRING.EYES:IRREVERSIBLE DAMAGE & POSSIBLY
BLINDNESS.CHRONIC-DERMATITIS,BRONCHITIS,CHRONIC RUNNY NOSE &
BLEEDING.
Effects of Overexposure:SPRAY OR MISTS ARE SEVERELY IRRITATING TO THE
EYES & RESPIRATORY TRACT. CAUSING TICKLING OF THE NOSE AND THROAT.
CAUSES CHARRING OF THE SKIN AS A RESULT OF THE GREAT AFFINITY FOR,
AND STRONG EXOTHERMI C REACTION WITH WATER. SWALLOWING CAN CAUSE
SEVERE DAMAGE OF MUCOUS MEMBRANES.
Medical Cond Aggravated by Exposure:SKIN IRRITATION MAY BE AGGRAVATED
IN PERSONS WITH EXISTING SKIN LESION. BREATHING OF SPRAYS (SULFURIC
ACID MISTS) MAY AGGRAVATE ACUTE OR CHRONIC ASTHMA AND OTHER CHRONIC
PULMONARY DISEASE.

First Aid:SPEED IS ESSENTIAL.START FIRST AID & GET MEDICAL CARE AT
ONCE.EYES:HOLD EYELID OPEN & FLUSH WITH WATER FOR 15
MINUTES.SKIN:WIPE EXCESS WITH A DRY CLOTH.THEN WASH WITH PLENTY OF
WATER & SOAP.INHALATION :REMOVE TO FRESH AIR.GIVE CPR/OXYGEN
IFNEEDED.INGESTION:GET MEDICAL ATTENTION AT ONCE.

Flash Point:NONE
Extinguishing Media:EXPECT VIOLENT REACTION WITH WATER. USE DRY
CHEMICAL OR CARBON DIOXIDE.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS.FIGHT FIRE FROM A
SAFE DISTANCE.USE ACID RESISTANT EQUIPMENTS.
Unusual Fire/Explosion Hazard:SULFUR OXIDES.USE CARE.WATER APPLIED
DIRECTLY TO THIS ACID RESULTS IN EVOLUTION OF HEAT,SPATTERING & A
VIOLENT REACTION CAUSING NEARBY COMBUSTIBLES TO IGNITE.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT.STOP LEAK IF
POSSIBLE.SMALL SPILLS SHOULD BE COVERED WITH NA BICARBONATE,SODA
ASH,OR LIME.AVOID FOAMING/SPATTERING.PICK UP WITH ABSORBING
MATERIAL & TRANSFER TO A SUITABLE CH EMICAL WASTE CONTAINER.DON'T
WASH IT DOWN TO SEWER
Neutralizing Agent:LIME OR SODA

Handling and Storage Precautions:STORAGE-STORE IN COOL,DRY PLACE.AVOID
EXCESSIVE HEAT & BELOW FREEZING TEMPERATURES.
Other Precautions:KEEP IN AN AREA WITH AN ACID RESISTANT CEMENT FLOOR.
DO NOT BREATHE SPRAYS OR MISTS. DO NOT INGEST. DO NOT GET IN EYES,
ON SKIN OR ON CLOTHING. KEEP OUT OR THE REACH OF CHILDREN. DO NOT
COMBINE WITH A LKALINE DRAIN CLEANERS.

Respiratory Protection:USE NIOSH/MSHA APPROVED MIST FILTER, ACID GAS
CARTRIDGE RESPIRATOR. USE POSITIVE PRESSURE SELF-CONTAINED
BREATHING APPARATUS FOR EMERGENCY CONDITIONS WHERE EXPOSURE LIMITS
ARE EXCEEDED.
Ventilation:LOCAL EXHAUST
Protective Gloves:RUBBER OR PVC
Eye Protection:SPLASH-PROOF SAFETY GOGGLES/FACE SHIELD
Other Protective Equipment:MAINTAIN A SINK,SAFETY SHOWER,EYEWASH
FOUNTAIN IN WORK AREA.HAVE OXYGEN READILY AVAILABLE.FULL-BODY
PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH HANDS BEFORE EATING OR DRINKING.
Supplemental Safety and Health

HCC:C1
Boiling Pt:B.P. Text:440F,227C
Spec Gravity:1.775
pH:< 1
Solubility in Water:COMPLETE
Appearance and Odor:DARK AMBER LIQUID WITH VERY SLIGHT ACID ODOR

Stability Indicator/Materials to Avoid:YES
ORGANICS,CHLORATES,CARBIDES,FULMINATES,PICRATES,METALS,WATER.REACTION
WITH METALS->HIGHLY FLAMMABLE HYDROGEN GAS.
Stability Condition to Avoid:WHEN DILUTING, ACID SHOULD BE ADDED TO
DILUENT, DO NOT ADD DILUENT TO SULFURIC ACID.
Hazardous Decomposition Products:TOXIC GAS AND VAPORS SUCH AS SULFURIC
ACID FUMES AND OXIDES OF SULFUR MAY BE RELEASED ON DECOMPOSITION.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
LOCAL, STATE AND FEDERAL REGULATIONS.THIS MATERIAL IS RCRA
HAZARDOUS WASTE D002,CORROSIVE & D003,REACTIVE.SPILLS ARE SUBJECT
TO CERLCA REPORTING REQUIREMEN TS:RQ=1000 LBS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.